|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|63761||48251||2016||5 صفحه PDF||سفارش دهید||دانلود کنید|
A mild and simple process for the effective oxidation of 5-hydroxymethylfurfural (HMF) into 2,5-diformylfuran (DFF) has been developed using NaNO2 as the oxidant. Some important reaction parameters were investigated to optimize the oxidation of HMF into DFF. It was found that the reaction solvent was very crucial for this reaction. Trifluoroacetic acid was the best solvent for the oxidation of HMF into DFF by NaNO2. Under the optimal reaction condition, almost quantitative HMF conversion and high DFF yield of 90.4% were obtained after 1 h at room temperature.
A mild and simple process for the effective oxidation of 5-hydroxymethylfurfural (HMF) has been developed by the use of cheap oxidant NaNO2, and possible reaction routes are discussed.Figure optionsDownload as PowerPoint slide
Journal: Journal of Energy Chemistry - Volume 25, Issue 1, January 2016, Pages 117–121