کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
639266 | 1456190 | 2006 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetic analysis on reactive extraction of aspartic acid from water in hollow fiber membrane modules
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The simultaneous extraction and stripping of aspartic acid (Asp) in two microporous hollow fibers was studied, in which di(2-ethylhexyl)phosphoric acid (D2EHPA) dissolved in kerosene was used as carriers. Aspartic acid was extracted from an aqueous feed phase to the organic phase in the extraction module, and the loaded Asp was then stripped to an aqueous phase in the stripping module. Experiments were conducted at a fixed feed concentration of Asp (5Â mol/m3) and different feed pH (3-5), carrier concentrations (100-500Â mol/m3), and strip acidities (100-2000Â mol/m3). The flow rates were varied in the range 120-420Â cm3/min for feed phase, 180-480Â cm3/min for organic phase, and 240-600Â cm3/min for strip phase. It was shown that the rate of Asp extraction increased with increasing feed and strip flow rates; however, the effect of organic flow rate was negligible. A steady-state mass transfer model was developed that considers all possible diffusion resistances to predict time changes of the extent of Asp extraction in these two hollow fiber modules. Finally, the rate-controlling mechanisms of such non-dispersive solvent extraction processes were identified and discussed by comparing the relative resistance of each mass transfer step.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 281, Issues 1â2, 15 September 2006, Pages 186-194
Journal: Journal of Membrane Science - Volume 281, Issues 1â2, 15 September 2006, Pages 186-194
نویسندگان
Su-Hsia Lin, Chia-Nan Chen, Ruey-Shin Juang,