کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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639451 | 1456197 | 2006 | 9 صفحه PDF | دانلود رایگان |

Highly efficient Pd membranes supported on porous ceramic tubes were synthesized by a modified electroless plating method and utilized in H2 enrichment from the gas mixture that came from an NH3 cracker. Two Pd membranes whose permeation properties varied widely had been evaluated at temperatures ranging from 623 to 773 K and under pressures up to 5.06625 × 105 Pa (5.0 atm). Experimental results revealed that the concentration polarization phenomenon played a determining role in the case of gas separation by the highly permeable and selective membranes. It caused a significant loss in both H2 yield and purity; and therefore, the separation efficiency of H2 generation system decreased greatly. A mathematical model was built to describe the concentration polarization phenomena in H2 enrichment by highly permeable and selective Pd membranes under the conditions utilized. In line with the experimental observations, this model accurately predicated the dependency of permeation performance on the operation parameters such as pressure, temperature, feed gas flow rate and permeability.
Journal: Journal of Membrane Science - Volume 274, Issues 1–2, 5 April 2006, Pages 83–91