کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
64034 | 48266 | 2014 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Efficient fixation of CO2 at mild conditions by a Cr-conjugated microporous polymer Efficient fixation of CO2 at mild conditions by a Cr-conjugated microporous polymer](/preview/png/64034.png)
We reported a bifunctional material, Cr-salen implanted conjugated microporous polymer (Cr-CMP), which is able to capture excellent CO2 amounts and has a remarkable catalytic activity towards the cycloaddition reaction of CO2 to epoxides forming cyclic carbonates at mild conditions without additional solvents. This heterogeneous Cr-CMP catalyst has a superior catalytic activity to its related homogeneous catalyst and can be reused more than ten times without a significant decrease in catalytic activity.
Graphical AbstractA Cr-salen implanted conjugated microporous polymer (Cr-CMP) can capture excellent CO2 amounts and catalyze the cycloaddition reaction of CO2 to form cyclic carbonates under mild conditions without additional solvents.Figure optionsDownload as PowerPoint slide
Journal: Journal of Energy Chemistry - Volume 23, Issue 1, January 2014, Pages 22–28