کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
643216 884361 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Caprolactam recovery by a column packed with polysulfone microcapsules containing 1-octanol
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Caprolactam recovery by a column packed with polysulfone microcapsules containing 1-octanol
چکیده انگلیسی

Caprolactam recovery from its dilute aqueous solution is a challenging task in industry. To save resources and protect environment, a caprolactam recovery technology based on extractant microcapsules as the separation material was introduced. In this new technology, polysulfone microcapsules containing 1-octanol were packed in a column. In the extraction process, recovery ratio of 0.99 was achieved within 0.6 bed volume. More than 10 theoretical plates per meter microcapsule column were realized. In the regeneration process, sulfuric acid aqueous solution was introduced as the stripping agent. Accordingly the new technology can be integrated with existing caprolactam production process because the eluent could be returned to NH3 causticization section. Caprolactam was successfully stripped and concentrated. Caprolactam concentration of 112 g/L in the eluent was obtained. New technology based on extractant microcapsules shows high efficiency in caprolactam recovery.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 69, Issue 1, 15 September 2009, Pages 71–77
نویسندگان
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