کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6455177 | 1419023 | 2016 | 4 صفحه PDF | دانلود رایگان |
- Modification of a heterogeneous catalyst by coating it with SiO2.
- ε-caprolactam was produced through Beckmann rearrangement in mild conditions.
- The proposed method is a promising approach for saving time in large scale production.
In this work and in continuation of our strategy for improving the performance of heterogeneous catalysts, the SiO2@GO-OSO3H catalyst was applied as a very efficient solid acid catalyst for the Beckmann rearrangement. This catalyst effectively catalyzed the liquid-phase Beckmann rearrangement of cyclohexanone oxime to caprolactam in high yield under very mild conditions. The improvement of GO-OSO3H catalyst in regard to its separation from reaction mixture is achieved by coating it with a mesoporous SiO2 layer. The influence of the operating parameters on the performance of the catalyst namely solvent, temperature, amount of catalyst, and time was studied.
Journal: Catalysis Communications - Volume 87, 5 December 2016, Pages 70-73