کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6456465 1419919 2017 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Editor's choice paperOxidation of aliphatic and aromatic CH bonds by t-BuOOH catalyzed by μ-nitrido diiron phthalocyanine
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Editor's choice paperOxidation of aliphatic and aromatic CH bonds by t-BuOOH catalyzed by μ-nitrido diiron phthalocyanine
چکیده انگلیسی


- Formation of the diiron peroxo complex Fe(IV)NFe(III)OOtBu.
- Homolytic cleavage of OO bond leads to two active species reacting with CH bonds.
- Oxidation of cyclohexane, cyclohexene, toluene and benzene.

Low temperature selective transformation of alkanes to useful products continues to be an important challenge in chemistry and industry. μ-Nitrido diiron phthalocyanines in combination with H2O2 have been recently identified as powerful oxidation catalysts for these challenging reactions due to the formation of ultra-high valent diiron oxo species PcFe(IV)μNFe(IV)O(Pc+). This very strong two-electron oxidizing species is generated from peroxo complex PcFe(IV)μNFe(III)OOR(Pc) (RH in the case of H2O2) via heterolytic OO bond cleavage. Therein we show that the evolution of the peroxo diiron complex depends on the peroxide structure. Using tBuOOH we have demonstrated the formation of an one-electron oxidizing PcFe(IV)μNFe(IV)O(Pc) and tBuO radical via homolytic OO cleavage of the peroxocomplex. The reactivity of the μ-nitrido diiron tetra-t-butylphthalocyanine − tBuOOH catalytic system was investigated in the oxidation of different CH bonds in alkanes, olefins, aromatic and alkylaromatic compounds. The main products of cyclohexane oxidation were cyclohexanone and cyclohexanol whereas bicyclohexyl was formed in minor amounts even in the presence of O2 and tBuOOH. Under optimal conditions, the turnover numbers of almost 5300 have been achieved.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 426, Part B, January 2017, Pages 499-505
نویسندگان
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