کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6464988 1422946 2018 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
3D spongy CoS2 nanoparticles/carbon composite as high-performance anode material for lithium/sodium ion batteries
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
3D spongy CoS2 nanoparticles/carbon composite as high-performance anode material for lithium/sodium ion batteries
چکیده انگلیسی


- CoS2/C assembled by CoS2 nanoparticles anchored on spongy carbon is presented.
- As anode materials for LIBs/SIBs, the composite shows good performances.
- This synthesis route can be used to synthesize other metal sulfides composite.

A spongy CoS2/carbon composite assembled from CoS2 nanoparticles (∼20 nm) homogeneously anchored on a spongy carbon matrix was synthesized through a facile freeze-drying method and a hydrothermal process. As anode material for lithium/sodium ion batteries (LIBs/SIBs), this composite shows significantly enhanced lithium/sodium storage performance with the synergetic effects due to the electrical conductivity of the carbon matrix and the porous structure, which provide buffer spaces for volume expansion during charge/discharge processes and feasible transfer pathways for electrons/ions. The electrochemical results demonstrate that the spongy CoS2/carbon composite is an outstanding anode material for LIBs and SIBs. It delivers a high specific capacity of 610 mAh g−1 at 500 mA g−1 after 120 cycles in LIBs and 330 mAh g−1 at 500 mA g−1 after 60 cycles in SIBs, respectively. Moreover, the freeze-drying/hydrothermal process developed in this work could be useful for the construction of many other high-capacity metal sulfide composites as electrode materials for sodium ion batteries.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 332, 15 January 2018, Pages 370-376
نویسندگان
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