کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6465053 | 1422951 | 2017 | 9 صفحه PDF | دانلود رایگان |
- A model describing perchlorate reduction in a methane-based MBfR was developed.
- The model was verified by experimental data under different operational conditions.
- The stratified microbial distribution in the biofilm was reveal by model analysis.
- Over 80% perchlorate removal efficiency can be achieved with proper PCH4 and LClO4.
- The perchlorate reduction could be affect by nitrate and nitrite concentrations.
Perchlorate (ClO4â) is recognized as an important contaminant in surface water and groundwater, which would pose health risks at very low concentrations. A methane-based membrane biofilm reactor (MBfR) has been successfully demonstrated for perchlorate reduction, which provided an alternative solution for perchlorate remediation with low cost. In this work, a multispecies biofilm model was developed to evaluate perchlorate reduction in the methane-based MBfR under different operational conditions. The model was calibrated and validated using the experimental data from the long-term operation of the MBfR at seven distinct stages. The results suggested that the developed model could satisfactorily describe perchlorate reduction and denitrification performances in the MBfR (R2 > 0.9). The modeling results provided insight into the microbial community distribution in the biofilm, with aerobic methanotrophs and perchlorate reduction bacteria being mainly located at the membrane side (â¼60%) and heterotrophic bacteria being situated near the liquid side (â¼50%). The model simulations indicated that over 80% of perchlorate removal efficiency could be achieved through controlling the optimal combinations of methane pressure (PCH4) and perchlorate loading (LClO4) (e.g., applying a PCH4 of 30 kPa at a LClO4 of 0.08 g Cl/m2/d). In addition, the perchlorate reduction would be inhibited by the presence of nitrate and nitrite in the MBfR, which should be appropriately controlled during the future practical application of the promising process.
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Journal: Chemical Engineering Journal - Volume 327, 1 November 2017, Pages 555-563