کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6465355 | 1422950 | 2017 | 11 صفحه PDF | دانلود رایگان |
- Water-soluble PIL microgel was used as a soft template and phosphorus dopant.
- Nitrogen, phosphorus co-doped mesoporous graphene framework was obtained.
- Its specific area and pore structure could be adjusted with microgel content.
- High capacitance and excellent ORR catalytic activity were achieved.
In this work, we endowed the hydrophobic triphenylphosphine (TPP) with vinyl group as a new copolymerization monomer to synthesize water-soluble microgels, in which the hydrophilic and positively charged TPP-derived chain segments are mainly located at the surface. These synthesized microgel is simultaneously used as a soft template and phosphorus dopant to fabricate nitrogen, phosphorus co-doped mesoporous graphene framework (NP-PG) via a facile hydrothermal process containing graphene oxide and ammonia. Self-assembly of graphene oxide sheets and microgels induced by their electrostatic interaction enable a tight contact between them, which would confine the phosphorus doping mostly in the pore walls. The obtained NP-PG, as a metal-free electrocatalyst for oxygen reduction, shows a comparable electrocatalytic activity to commercial Pt/C catalyst with a peak potential of â0.18Â V (vs. Ag/AgCl) and long-term durability. Additionally, it can also be used as a supercapacitor electrode to achieve a high specific capacitance of 245Â FÂ gâ1 at 0.5Â AÂ gâ1 and 95% of capacitance retention even after 3000Â cycles at 5Â AÂ gâ1.
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Journal: Chemical Engineering Journal - Volume 328, 15 November 2017, Pages 417-427