کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6465728 | 1422956 | 2017 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Facile preparation of cross-linked polyimide aerogels with carboxylic functionalization for CO2 capture Facile preparation of cross-linked polyimide aerogels with carboxylic functionalization for CO2 capture](/preview/png/6465728.png)
- Cross-linked PI aerogel was prepared by sol-gel process and supercritical drying.
- The PI aerogel has a high-performance for CO2 adsorption due to the carboxyl.
- High yield and flexible processing are benefit for the formation of membrane.
In this study, highly cross-linked and completely imidized polyimide aerogels containing carboxyl groups were successfully synthesized using a mild sol-gel method at room temperature from 3,5-diaminobenzoic (DABA) and biphenyl-3,3â²,4,4â²-tetracarboxylic (BPDA) and cross-linked with 1,3,5-triaminophenoxybenzene. The densities of the obtained polyimide aerogels are between 0.116 and 0.386 g/cm3, the specific surface areas range from 173 to 461 m2/g, and the porosities are as high as 97%. The CO2 adsorption-desorption isotherms are reversible, and the CO2 uptakes at 25 °C and 1 bar are as high as 21.10 cm3/g, which are comparable to those of previously reported microporous organic polymers. The high CO2 adsorptions are attributed to the abundance of electron-rich heteroatoms in the polyimide networks and to the presence of carboxyl groups, a type of CO2-philic group. The facile preparation and high CO2 adsorptive capacity indicate that polyimide aerogels may be ideal candidates for capturing CO2.
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Journal: Chemical Engineering Journal - Volume 322, 15 August 2017, Pages 1-9