Removal of perfluorooctanoic acid from water with economical mesoporous melamine-formaldehyde resin microsphere

- Mesoporous melamine-formaldehyde resin microsphere was fabricated.
- It had high adsorption amount of perfluorooctanoic acid than activated carbon.
- The adsorption can be performed in a wide pH and temperature range.
- The material could be well regenerated by dilute ammonia solution.
- It was a potential adsorbent to remove perfluorooctanoic acid from water.

Perfluoroalkyl and polyfluoroalkyl substances are priority contaminants of global concern. It is urgent to remove them from the environment. Adsorption is an efficient approach, but the adsorption capacity and regeneration of adsorbent were not satisfactory. In the present study, mesoporous melamine-formaldehyde resin microsphere (MMFRS) was fabricated through suspension polymerization. Owing to its mesoporous property and large anion-exchange capacity of 0.3 mmol/g, MMFRS was applied to the adsorption of perfluorooctanoic acid, a model target. The sorption kinetics obeyed pseudo-second-order equation and the sorption isotherms fitted both Freundlich and Langmuir models well. MMFRS exhibited a superiority over commercial powdered activated carbon on the adsorption amount. The sorption could reach equilibrium within 24 h. In addition, the material could be easily and economically regenerated by dilute NH3·H2O (7.5 mM); a regeneration percentage (>85%) after 20 recycles was obtained. This study provides a facile, environmentally-friendly and low energy-consumption strategy for removal of perfluorooctanoic acid from aqueous solution in waste-water treatment.

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