کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6475068 1424968 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Numerical study assessing various ammonia/methane reaction models for use under gas turbine conditions
ترجمه فارسی عنوان
مطالعه عددی مدل های واکنش آمونیاک / متان مختلف برای استفاده در شرایط توربین گاز
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
Ammonia as an alternative fuel and hydrogen carrier has received increased attention in recent years. To explore the potential of co-firing ammonia with methane for power generation, studies involving robust mathematical analyses are required to progress towards industrial implementation. To explore a best suited mechanism for ammonia/methane combustion in gas turbines, five different detailed mechanisms were compared to identify their accuracy to represent the reaction kinetics under real gas turbine combustor conditions. Ignition delay time was compared with recent literature showing that the mechanisms of Tian and Teresa exhibit the best accuracy over a large range of conditions. A 1D simulation was also conducted using a Chemical Reactor Network (CRN) model, thus providing a relatively quick estimation of the combustion mechanisms under swirling combustion conditions. The simulation of NOx emissions indicates that Tian mechanism has better performance than the others compared. Hence, the Tian mechanism was selected as the most appropriate for further studies of ammonia/methane combustion through a set of experiments carried out at various equivalence ratios and pressure conditions. Finally, sensitivity and pathway analyses were also performed to identify important reactions and species under high pressurized conditions, areas that need more attention for model development and emission control in future studies.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 196, 15 May 2017, Pages 344-351
نویسندگان
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