کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6475416 | 1424970 | 2017 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Extraction and mechanism for the separation of neutral N-compounds from coal tar by ionic liquids Extraction and mechanism for the separation of neutral N-compounds from coal tar by ionic liquids](/preview/png/6475416.png)
- The selected ILs shows good extraction performance for neutral N-compounds.
- The mechanism of the extraction was confirmed to be the formation of hydrogen bond.
- BmimCl can be easily regenerated and recycled with good performance even 5 times.
- A green approach was provided for the separation of neutral N-compounds from coal tar.
Coal tar is one of the valuable chemical materials and energy, from which the nitrogen-containing compounds (N-compounds), indole, carbazole, pyridine, and quinoline, are mainly separated. In the present work, the imidazolium-based ILs with different anions, 1-butyl-3-methyl-imidazolium chloride (BmimCl), 1-butyl-3-methyl-imidazolium bromide (BmimBr), 1-butyl-3-methyl-imidazolium tetrafluoroborate (BmimBF4), 1-butyl-3-methyl-imidazolium disulfate (BmimHSO4), and 1-butyl-3-methyl-imidazolium acetate (BmimCH3COO), were used to separate those N-compounds via extraction. The performances of ILs extraction were evaluated by the extraction efficiency and distribution coefficient. High extraction efficiency and selectivity could be found for the neutral N-compounds, indole and carbazole, by BmimCl than basic N-compounds, pyridine and quinoline. Meanwhile, the optimized conditions were ascertained and the selected ILs could be easily regenerated by water and be sustainable recycled by a back-extraction process. Furthermore, a hydrogen bond was formed between the neutral N-compound and the selected ILs, and the mechanism was confirmed based on the analysis by a molecular simulation. Thus, an approach was provided for the separation of neutral N-compounds from coal tar.
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Journal: Fuel - Volume 194, 15 April 2017, Pages 27-35