Slagging behaviors of high alkali Zhundong coal during circulating fluidized bed gasification

- Slagging behaviors of Zhundong coal during CFBG for 72 h were investigated.
- Corrosion-reduced slagging was occurred at wall temperature above 495 °C.
- High density ash caused severe slagging on the circulating air pipe.
- Slags on the circulating air pipe were characterized with a layered structure.

Slagging behaviors of high alkali Zhundong coal during circulating fluidized bed (CFB) gasification were investigated in a 0.4 t/d CFB test rig for 72 h, with air-cooled ash deposition probes located along the gas flow direction. The microstructure, chemical compositions and mineral crystalline phases of ash were analyzed. Corrosion-reduced slagging and layered slagging were found on the ash deposition probes and the circulating air pipe, respectively. At the initial stage of corrosion-reduced slagging, Fe in the metal surface was transferred to an unsteady state by the corrosion of NaCl. Once corrosion occurred, the corrosion-reduced slagging was accelerated by the presence of sodium iron oxides and alkali sulfates. This type of slagging was greatly influenced by wall temperature, as it was more inclined to occur on the probes only at wall temperature above 495 °C. The high density of circulating ash, which was rich in Ca, Na, Fe, S, Si and Mg in the form of low-melting-temperature sulfates and silicates, resulted in slagging on the circulating air pipe. A layered structure was observed on the cross-section of the slags, and its characteristics were determined by the distributions of Ca, S, Na and Fe. With the growth of the slags, the air hole in the circulating air pipe was blocked due to the aggregation of stickier fusant, which might cause unscheduled outages.