کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6477013 1426210 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermophysical characterization of 1-ethylpyridinium triflate and comparison with similar ionic liquids
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Thermophysical characterization of 1-ethylpyridinium triflate and comparison with similar ionic liquids
چکیده انگلیسی


• A thermophysical characterization of 1-ethylpyridinium triflate is presented.
• The properties have been correlated with temperature.
• The density at T = 303.15 K at several pressures has been also measured.
• This study includes the thermal properties around the normal melting point.
• A comparison with similar ionic liquids has been established.

We present here a comprehensive thermophysical study of the piridynium-based ionic liquid: 1-ethylpyridinium triflate. Density, speed of sound, refractive index, surface tension, isobaric molar heat capacity, kinematic viscosity and electrical conductivity have been determined in the temperature range (293.15–338.15 K) and at pressure of 0.1 MPa, density was also measured in the pressure range (0.1–40 MPa) at T = 303.15 K. From these values, some derived properties have been calculated. In addition the thermal behaviour around the melting point has been registered. All these properties have been discussed and compared with those of two similar ionic liquids, 1-ethylpyridinium bis(trifluoromethylsulfonyl)imide and 1-butylpyridinium triflate.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 103, December 2016, Pages 395–402