کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
64949 | 48376 | 2015 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: The enantioselectivity of the manganese-salen complex in the epoxidation of unfunctionalized olefins and the influence of grafting The enantioselectivity of the manganese-salen complex in the epoxidation of unfunctionalized olefins and the influence of grafting](/preview/png/64949.png)
• Ab initio modelling of the influence of grafting of manganese-salen complexes.
• Asymmetric salen complexes exhibit reduced enantioselectivity.
• Asymmetric complex grafted to a metal organic framework via a stepwise procedure.
• A catalytic test shows the decrease in selectivity is limited, the MIL-101(Cr) structure is a good support.
Jacobsen’s complexes are famous for their usability for enantioselective epoxidations. However, the applicability of this catalytic system has been severely limited by several practical problems such as deactivation and separation after reaction. Grafting of Jacobsen-type complexes on solid supports is an attractive way to overcome these problems but led to a decrease in selectivity. A combined theoretical and experimental approach is presented to unravel the factors governing enantioselectivity. The importance of different substituents was determined by analyzing the transition state for the oxygen transfer using the full system as a model. An analysis of the asymmetric complex has shown an inherent tendency for a decreased selectivity due to the lack of specific bulky groups. Experimentally an immobilized Jacobsen catalyst on a metal organic framework (MIL-101) was synthesized which confirms the computational tendencies but the decrease in selectivity is limited, indicating that the MIL-101(Cr) is a suitable carrier for this complex.
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Journal: Journal of Molecular Catalysis A: Chemical - Volume 406, September 2015, Pages 106–113