The poisoning effect of heavy metals doping on Mn/TiO2 catalyst for selective catalytic reduction of NO with NH3

• Both of Zn and Pb had a poisoning effect on Mn/TiO2 and the poisoning effect of Zn was more obvious.
• The doping of Zn or Pb on Mn/TiO2 would lead to a great decrease of its reducibility.
• The doping of Zn or Pb on Mn/TiO2 results in a great decrease of NO adsorption capacity.
• The decrease of surface area is the main reason for the decline of NH3 adsorption capacities of Zn-Mn/TiO2 and Pb-Mn/TiO2.

Heavy metals have been proven to be of deactivation effect on SCR catalyst. In this paper, the poisoning effect of heavy metals (Zn and Pb) on Mn/TiO2 catalyst was investigated based on experimental and theoretical study. It was found that both of Zn and Pb had a poisoning effect on Mn/TiO2 catalyst and the poisoning effect of Zn was more obvious. The characterization results indicated that the doping of heavy metals on Mn/TiO2 surface would lead to a great decrease of reducibility, surface acidity and NO adsorption ability. The results of XPS characterization revealed the decrease of Mn4+ atomic concentration and chemisorbed oxygen species caused by the doping of heavy metals. Based on the above mentioned unfavorable properties, the doping of heavy metals would cause a serious deactivation of Mn/TiO2 catalyst. From the results of DFT calculations, it could be concluded that the doping of heavy metals on Mn/TiO2 catalyst resulting in a great decrease of NH3 adsorption capacity and NO adsorption ability, which agrees well with the experimental results.

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