کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
65201 48386 2015 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structure and catalytic activity of 3D macro/mesoporous Co3O4 for CO oxidation prepared by a facile self-sustained decomposition of metal–organic complexes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Structure and catalytic activity of 3D macro/mesoporous Co3O4 for CO oxidation prepared by a facile self-sustained decomposition of metal–organic complexes
چکیده انگلیسی


• 3D macro/mesoporous Co3O4 was successfully synthesized by a flash synthesis.
• Porous Co3O4 exhibits the hierarchically porous morphology.
• Porous Co3O4 shows 100% conversion efficiency of CO to CO2 at 140 °C.
• Porous Co3O4 is more efficient for CO oxidation than Co3O4 nanoparticles.

Three-dimensional macro/mesoporous tricobalt tetraoxide Co3O4 was prepared via a facile self-sustained decomposition using the complexes of metallic salts and organics (metal–organic complexes). Porous Co3O4 material was characterized using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, and X-ray photoelectron spectrum (XPS) to examine the morphology and microstructure to find out the cause. Co3O4 with the 3D hierarchical porous structure consisting of nanoparticles has a coral-like shape with a size of tens of micrometers and exhibits the hierarchically porous morphology, in which the walls of the macropores contain smaller mesopores. The catalytic performance of the porous Co3O4 for CO oxidation has been studied with a continuous flow fixed-bed quartz microreactor. The porous Co3O4 exhibits excellent catalytic activity for CO oxidation, the CO conversion rate reaches 100% at 140 °C.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 398, March 2015, Pages 79–85
نویسندگان
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