کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
65543 | 48395 | 2014 | 7 صفحه PDF | دانلود رایگان |

• MCM-41-Imi/Br showed synergistic action for the ring opening of epoxides.
• The mechanism of the ring opening process by MCM-41-Imi/Br was investigated.
• No solvent was necessary for liquid substrates.
Imidazole was immobilized on MCM-41 using 3-chloropropyltriethoxysilane (CPTES) as the anchoring agent followed by alkylation with 1,2-dibromoethane at 110 °C. The resulting catalyst was designated as MCM-41-Imi/Br. The catalyst was used for the synthesis of cyclic carbonates via cycloaddition of CO2 with several epoxides under solvent free condition. The use of MCM-41-Imi (without bromide ion) to catalyze the reaction led to the elucidation of the reaction mechanism involved in the synergistic catalysis. The catalyst was used in the cycloaddition of styrene oxide, epichlorohydrine, glycidol, allyl glycidyl ether and phenyl glycidyl ether. A high yield and excellent selectivity of cyclic carbonates were obtained under optimized conditions. The yields of the respective cyclic carbonates were 98.8% for styrene oxide, 97.0% for epichlorohydrin, 98.3% for glycidol, 97.5% for allyl glycidyl ether, 96.7% for phenyl glycidyl ether and 100% for 1,2-epoxyhexane.
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Journal: Journal of Molecular Catalysis A: Chemical - Volume 386, May 2014, Pages 42–48