کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
65692 48400 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Impact of nature and length of linker on the catecholase activity of a covalently immobilized copper(II) complex in continuous flow catalysis
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Impact of nature and length of linker on the catecholase activity of a covalently immobilized copper(II) complex in continuous flow catalysis
چکیده انگلیسی


• A copper(II) complex covalently grafted on graphite felt support.
• Influence of the chain nature and length on the catalytic activity.
• Increasing catecholase activity with chain length of linkers.
• Higher catecholase activity with linkers containing polyoxoethylene units.

The catecholase activity of four immobilized mononuclear copper(II) catalysts with chains of different nature and length used as linkers is studied in continuous flow catalysis. The graphite felt support was first derivatized by cathodic reduction of 4-carboxymethyl-benzenediazonium salts. Complexes with different chains were then covalently immobilized on the functionalized porous support by esterification reaction. The successful achievement of the immobilization process is attested by the presence of the CuII/I reversible system in cyclic voltammetry. Volume concentrations around 10−8 mol cm−3 of immobilized catalysts are estimated by integration of the redox peak. Comparison of the catecholase activity of the immobilized complexes allows to conclude on the effect of the chain nature and length. First, high chain length positively influences the catalytic activity. Second, the presence of oxygen atoms in the linker significantly enhances the catecholase activity of the catalyst. A possible explanation is the chain hydrophilicity, making easier the access of the catalytic center by H2O molecules.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 377, October 2013, Pages 51–56
نویسندگان
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