کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6578884 | 1422930 | 2018 | 34 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Degradation of chloramphenicol using a combination system of simulated solar light, Fe2+ and persulfate
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Solar irradiation (λâ¯â¥â¯290â¯nm) has been introduced into a traditional Fe2+ activated persulfate (PS) system (Fe2+/PS). The combination system of solar light, Fe2+ and PS system (solar/Fe2+/PS) exhibited a rapid and continuous oxidation of chloramphenicol (CAP) in solution, and showed great advantages over the Fe2+/PS process by accelerated degradation efficiency. A presumed reason is that Fe2+ was slowly and continuously recycled by solar light, and the reductive photolysis Fe3+ to Fe2+ was promoted concomitantly with the production of additional hydroxyl radical (HO). The optimal dosages of PS and Fe2+ were determined by batch experiments. pH significantly influenced CAP degradation, and an acidic condition favored the reaction. Both HO and sulfate radical (SO4â) were considered to be the mainly oxidant to remove CAP, and HO had a higher contribution than SO4â. The presence of HCO3â, NO3â, NO2â, H2PO4â, HPO42â demonstrated adverse effects on CAP decay in solar/Fe2+/PS process. Coexisting Clâ ions slightly accelerated the CAP degradation rate at an appropriate concentration (0.6-6â¯mM) but gradually inhibited at a higher Clâ (12-36â¯mM) content. The results clearly showed that CAP presented the slowest degradation rate in wastewater, and the colloids should be taken into consideration prior to the application of solar/Fe2+/PS for wastewater treatment. Nonetheless, up to 89.7%, 94.7%, and 65.4% of CAP were removed from the filtrate, permeate, and retentate within 100â¯min, respectively. It is expected that the modified process could be applied for CAP removal from wastewater containing a considerable colloids/organic content. Finally, 8 major intermediate products were identified and the preliminary degradation pathways were proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 348, 15 September 2018, Pages 455-463
Journal: Chemical Engineering Journal - Volume 348, 15 September 2018, Pages 455-463
نویسندگان
Minghua Nie, Caixia Yan, Xiaoying Xiong, Xinmei Wen, Xue Yang, Zelan lv, Wenbo Dong,