کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
65801 | 48403 | 2013 | 7 صفحه PDF | دانلود رایگان |
• A series of novel FGBILs was synthsized by a simple method.
• The FGBILs was firstly used as catalysts for the cycloaddition reaction.
• The FGBILs show high catalytic activity and selectivity under mild conditions.
• Effects of the structure on the catalytic activity of FGBILs were investigated.
• A plausible mechanism for cycloaddition reaction over FGBILs was proposed.
A series of functional guanidinium-based ionic liquids (FGBILs) that contain both Lewis acid and basic sites was prepared by a simple method, and used as catalysts for the synthesis of cyclic carbonates through the cycloaddition of CO2 to epoxides in the absence of co-catalyst and solvent. Propylene oxide conversion was near completion at 130 °C and 2.5 MPa in 2 h when [TMGC2H4NH2]Br was used as catalyst. The effects of functional groups and counter anions on catalytic performance were investigated. The synergistic effect of polarization by hydrogen bonding and the nucleophilic attack by bromide anion account for the facile ring-opening of epoxide. Furthermore, the protocol is applicable to a variety of terminal epoxides, producing the corresponding cyclic carbonates in high yield and selectivity. It is envisaged that the metal- and solvent-free process using a single catalyst has high potential for large-scale fixation of CO2.
Figure optionsDownload high-quality image (154 K)Download as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 378, 1 November 2013, Pages 326–332