کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6582386 | 456353 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
CaO-loaded alginate capsule modified with silane coupling agents for transesterification of rapeseed oil with methanol
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The methanolysis of rapeseed oil to fatty acid methyl esters (FAME) using CaO-loaded alginate capsules modified with silane coupling agents is reported. A FAME yield of 87% was obtained with CaO-loaded alginate capsules after 6Â h at 333Â K. However, capsule breakage reached 18.8% after the first run. In contrast, the breakage was reduced to 2.6% by extra alginate shells modified with n-butyltrimethoxysilane. Consequently, the amount of Ca leaching into the FAME phase was decreased substantially, whereas the reaction induction and completion times were increased. Static diffusion experiments and analyses of the liquid phases inside and outside the capsules at each time interval indicated that the permeability of methanol is the most important factor for determining the induction and completion times.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 288, 15 March 2016, Pages 473-481
Journal: Chemical Engineering Journal - Volume 288, 15 March 2016, Pages 473-481
نویسندگان
Takeshi Furusawa, Fumio Kurayama, Miyuki Shiba, Ryosuke Kadota, Masahide Sato, Noboru Suzuki,