کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
658257 1458080 2013 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Quantification of the mass transport in a two phase binary system at elevated pressures applying Raman spectroscopy: Pendant liquid solvent drop in a supercritical carbon dioxide environment
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
Quantification of the mass transport in a two phase binary system at elevated pressures applying Raman spectroscopy: Pendant liquid solvent drop in a supercritical carbon dioxide environment
چکیده انگلیسی
Mass transport between organic solvents (S) and carbon dioxide (CO2) has been investigated at pressures below the mixture critical pressure (MCP). Acetone and dimethyl sulfoxide (DMSO) have been used as organic solvents. Profiles of the mixture composition have been measured through liquid solvent drops pendant at steady conditions in a pressurized CO2 environment. The drop has been kept steady by feeding exactly that amount of liquid through a feed glass capillary into the pendant drop that evaporated at the same time from the drop into the CO2 environment. The liquid fed into the pendant drop has been either pure organic solvent or organic solvent with some CO2 dissolved. Profiles of the mixture composition have been quantified applying an optical Raman line imaging technique and the respective involved mass transport mechanisms are discussed comprehensively. Evaporative cooling was shown to dominate the temperature change at the inner margin of the drop, while mixing enthalpies were shown to be of minor importance. By fitting a mass transport model to DMSO concentration profiles, calculated from the mass fraction composition profiles, the mass transport properties diffusivity D, Biot-number Bi and mass transfer coefficient β could be derived. When acetone has been used as solvent, no steady drops could be formed not allowing a model based quantification of the mass transport.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Heat and Mass Transfer - Volume 62, July 2013, Pages 729-740
نویسندگان
, , , ,