کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6583923 456359 2016 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A simple one-pot in-situ method for the synthesis of aluminum and lanthanum binary oxyhydroxides in chitosan template towards defluoridation of water
ترجمه فارسی عنوان
یک روش ساده یک گودال در محل برای سنتز اکسید هیدروکسید دوتایی آلومینیوم و لانتانیم در قالب کیتوزان به سمت دفلوئید شدن آب
کلمات کلیدی
کیتوزان، آلومینیوم، لانتانیم، مخلوط اکسی هیدروکسید، فلوراید، جذب،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
Aluminum and lanthanum binary oxyhydroxides on chitosan template (CS@ALMOH) was synthesized by greener in-situ one-pot method for defluoridation of drinking water. Characterization by FTIR, XPS, TGA/DSC and SEM with EDAX revealed that the material was a composite of chitosan and aluminum-lanthanum with primary particle size of micrometer level. The prepared material shows relatively fast adsorption kinetics to fluoride removal within 15 min, good adsorption capacity with wide pH ranges of 3-9 and selectivity. The mechanism of fluoride removal using the synthesized materials were by both electrostatic interaction as well as ion-exchange. Equilibrium sorption results were well described by Freundlich, Langmuir and D-R isotherms and the sorption capacities were approximately 49.54 mg/g for CS@ALMOH and 33.39 mg/g for ALMOH. The sorption process follows pseudo-second-order and intraparticle diffusion kinetic models. This bifunctional adsorbent with aluminum and lanthanum oxyhydroxides impregnated onto chitosan polymeric matrix exhibits a pronounced fluoride adsorption capacity over already reported materials in the literature and the resulting CS@ALMOH material can be used in a broad pH range, which suggests its great potential for the decontamination of fluoride polluted water. The suitability of the CS@ALMOH material has been tested with the field samples collected in a nearby fluoride endemic area.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 283, 1 January 2016, Pages 1081-1089
نویسندگان
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