کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6584448 | 456361 | 2015 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Upgrading of 4-methylanisole in a catalytic reactor with electric discharges: A novel approach to O-removal from bio-oils
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Lignocellulosic biomass is considered as a very promising alternative to replace fossil sources due to its abundance, consistency with environment and renewability. Conversion of lignin biomass to bio-oil by flash pyrolysis is considered recently due to its feasibility and economical profits. The produced bio-oil contains highly oxygenated compounds that require upgrading in order to be used as a fuel source. In this study, upgrading of 4-methylanisole as a model compound of lignin derived bio-oil was performed in a hybrid catalytic dielectric barrier discharge (DBD) plasma reactor under ambient temperature and atmospheric pressure. Different commercial catalysts including Pt-Cl, Ni-Mo, Co-Mo, Pt-Re and Ni supported on Al2O3 were packed between the two electrodes in the discharge zone. The effects of various catalysts on conversion of 4-methylanisole, discharge power (DP) to the rector, distribution of products and degree of deoxygenation were investigated. The highest 4-methylanisole conversion (98.7%) and deoxygenation degree (47%) were achieved in the presence of Pt-Cl/Al2O3 and Pt-Re/Al2O3 catalysts, respectively. The plasma catalysis system has a lower DP, electrode temperature and breakdown voltage compared to plasma alone. According to the results, the main products were 4-methylphenol, 2,4-dimethylphenol and p-xylene. The results indicated that the catalytic DBD plasma reactor is a promising tool for the upgrading of 4-methylanisole.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 281, 1 December 2015, Pages 227-235
Journal: Chemical Engineering Journal - Volume 281, 1 December 2015, Pages 227-235
نویسندگان
Hamed Taghvaei, Mohammad Bagher Hosseinzadeh, Shahin Rezazadeh, Mohammad Reza Rahimpour, Alireza Shariati,