کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6585982 456382 2015 51 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Modeling and experimental validation of carbon dioxide sorption on hollow fibers loaded with silica-supported poly(ethylenimine)
ترجمه فارسی عنوان
مدلسازی و اعتبار سنجی آزمایشی جذب دی اکسید کربن بر روی فیبرهای توخالی که با پلی (اتیلنیمین)
کلمات کلیدی
اسید آمین، مطالعات جنبشی توده، فیبر توخالی پلی (اتیلنیمیم)، مدل سازی تودهای،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
A mathematical model is developed for carbon dioxide adsorption on hollow fiber post infused with physically impregnated poly(ethylenimine) silica sorbent. The model includes detailed mass transfer mechanisms and is rigorously validated under different operating conditions of flue gas flow rate, number of fibers within the module, fiber length and particle size. A fundamental model formulation for the sorbent polymer diffusivity including the temperature and the sorbent concentration dependency is proposed. The proposed model formulation is based on free volume theory model of polymer diffusion and effectively predicts the experimental observations. The model is able to predict the breakthrough curves at many different operating conditions and module designs such as conditions with varied flue gas flow rate, fiber length, fiber packing fraction and support silica particle size. The concave trend in the temperature dependency of breakthrough capacity that shows a maximum around 45-60 °C is analyzed using the developed model.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 259, 1 January 2015, Pages 737-751
نویسندگان
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