کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
66043 48413 2012 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Cross coupling reactions of multiple CCl bonds of polychlorinated solvents with Grignard reagent using a pincer nickel complex
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Cross coupling reactions of multiple CCl bonds of polychlorinated solvents with Grignard reagent using a pincer nickel complex
چکیده انگلیسی

The nickel(II) complex of a bulky pincer-type ligand, N,N′-bis(2,6-diisopropylphenyl)-2,6-pyridinedicarboxamido, was examined for sp3–sp3 coupling of Grignard reagents with polychlorinated solvents. The nickel(II) complex catalyzed CC coupling of polychlorinated alkyl halides, such as dichloromethane (CH2Cl2), chloroform (CHCl3), and carbon tetrachloride (CCl4), with various Grignard reagents. The effective activation of multiple CCl bonds proceeded under ambient reaction conditions and within a short time (20 min). This catalyst displays the highest activity yet reported for this reaction type, with catalyst loading as low as 0.4 mol% and turnover frequency (TOF) as high as 724 h−1. The catalyst is capable of replacing all chlorine atoms with CC bond formations for all of the polychlorinated solvents under investigation. The catalytic process could prove to be an efficient method of remediation of toxic polychlorinated solvents while generating synthetically and commercially important chemicals.

Figure optionsDownload high-quality image (107 K)Download as PowerPoint slideHighlights
► An efficient nickel(II) complex of an amide based pincer ligand for sp3–sp3 coupling.
► CC coupling of polychlorinated alkyl halides with various Grignard reagents.
► Activation of multiple CCl bonds at room temperature and within a short period of time.
► Low catalyst loading (0.4 mol%) and high turnover frequency (724 h−1).

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volumes 363–364, November 2012, Pages 322–327
نویسندگان
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