کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
66136 48416 2012 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Highly selective aqueous heterogeneous oxygenation of hydrocarbons catalyzed by recyclable hydrophobic copper (II) phthalocyanine nanoparticles
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Highly selective aqueous heterogeneous oxygenation of hydrocarbons catalyzed by recyclable hydrophobic copper (II) phthalocyanine nanoparticles
چکیده انگلیسی

A novel aqueous catalytic method for selective epoxidation of olefins and oxidation of saturated hydrocarbons to ketones using aqueous solution of tetra-n-butylammonium peroxomonosulfate (TBAOX) containing water-insoluble copper (II) phthalocyanine nanoparticles has been developed. No surfactants, additives, toxic reagents or solvents were involved. The impressive turnover numbers obtained for CuPc in this oxidation system displayed the high catalytic activity and relative stability of catalyst. The effective dispersity of CuPc in aqueous solution of TBAOX which yielded particles with average size of 30 nm, was the most important factor to affect the reaction rate. The catalyst could easily be recovered and reused without loss of activity and the reduced form of starting oxidant (n-Bu4NHSO4) could also be recycled.

Figure optionsDownload high-quality image (121 K)Download as PowerPoint slideHighlights
► Nanoparticles of CuPc were formed in aqueous solution of n-Bu4NHSO5.
► CuPc nanoparticles catalyze heterogeneous oxidation reaction in water.
► The reactions proceed well in the absence of organic co-solvents and surfactants.
► The catalyst can be easily recycled and reused without loss of activity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 357, May 2012, Pages 141–147
نویسندگان
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