کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
66151 | 48417 | 2012 | 9 صفحه PDF | دانلود رایگان |
N-sulfonic acid poly(4-vinylpyridinium) chloride is easily prepared by the reaction of poly(4-vinylpyridine) with neat chlorosulfonic acid. This reagent can be used as an efficient catalyst for the preparation of 1,1-diacetates at room temperature and neat condition. Deprotection of the resulting 1,1-diacetates can also be achieved using the same catalyst in methanol. This new method consistently has the advantages of excellent yields and short reaction times. Further, the catalyst can be reused and recovered for several times.
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► Synthesis of N-sulfonic acid poly(4-vinylpyridinum) chloride (NSPVPC).
► Characterization and application of NSPVPC for the acylation of aldehydes and deprotection of the obtained 1,1-diacetates.
► Catalysis under solvent-free conditions.
► Heterogeneous catalysis and recyclability of the catalyst.
Journal: Journal of Molecular Catalysis A: Chemical - Volume 356, April 2012, Pages 61–69