کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6619146 | 1424487 | 2018 | 37 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermodynamic properties of dilute hydrogen in supercritical water
ترجمه فارسی عنوان
خواص ترمودینامیکی هیدروژن رقیق شده در آب فوق بحرانی
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
A thermodynamic model is developed to calculate the fugacity coefficients and partial molar volumes of hydrogen at infinite dilution in water at 647.1-2000 K and pure water densities between 0 and 1500 kg mâ3. The model is based on the predicted values of DCFI (the dimensionless integral of the infinite dilution hydrogen - water direct correlation). Values of DCFI at low water densities are calculated from accurately known second cross virial coefficients; at high water densities predictions are based on the relations from the theory of a mixture of hard spheres; DCFI values at intermediate water densities are interpolated using a variant of corresponding-states correlation. Predicted values of the hydrogen fugacity coefficients at infinite dilution in water are compared with experimental data and results of the literature equations of state. The included Excel spreadsheet allows calculations provided that values of T, P, Ï1â, and κT for pure water are entered by a user.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 470, 25 August 2018, Pages 140-148
Journal: Fluid Phase Equilibria - Volume 470, 25 August 2018, Pages 140-148
نویسندگان
Andrey V. Plyasunov, Elena F. Bazarkina,