کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6619360 1424499 2018 32 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Liquid densities for n-decane + p-xylene mixtures from 293.15 K to 363.15 K at pressures up to 60 MPa
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Liquid densities for n-decane + p-xylene mixtures from 293.15 K to 363.15 K at pressures up to 60 MPa
چکیده انگلیسی
The experimental measurements for liquid densities of n-decane and p-xylene binary mixtures were performed over the entire composition with a high-pressure vibrating-tube densimeter. The temperature ranges for the present measurement were from 293.15 K to 363.15 K and the pressures were reached to 60 MPa. The experimental uncertainty is estimated to be 0.001 with 0.95 confidence level. Experimental density values were fitted by the modified Tammann-Tait equation. The PC-SAFT equation of state and Cibulka's equation was used to predict the densities of n-decane and p-xylene and its mixtures. In addition, derived volumetric properties, such as the excess molar volumes, the isothermal compressibility, and isobaric thermal expansivity, were calculated from the experimental density data. The effects of pressure and temperature on the derived properties were also discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 458, 25 February 2018, Pages 142-152
نویسندگان
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