کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6619414 | 460525 | 2016 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solubility of disodium 4,4â²-dinitrobibenzyl-2,2â²-disulfonate in aqueous organic solutions and its effects on the oxidation reaction of DSD acid synthesis
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The solubility of disodium 4,4â²-dinitrobibenzyl-2,2â²-disulfonate (DNDNa) in aqueous ethylene glycol monoethyl ether solution and aqueous ethylene glycol monobutyl ether solution was measured over the temperature range from 278 to 334Â K at atmospheric pressure by a dynamic method. The solubility of DNDNa in aqueous ethylene glycol monoethyl ether solution and aqueous ethylene glycol monobutyl ether solution increased with temperature over all solvent mixture compositions investigated. A synergistic effect on DNDNa solubility was observed with the maximum solubility at solute-free mass fraction of ethylene glycol monoethyl ether w30=0.6003 and solute-free mass fraction of ethylene glycol monobutyl ether w40=0.4054 , respectively. The solubility data were correlated using the electrolyte non-random two-liquid model and model parameters were determined simultaneously. It was found that around 0.4 (solute-free mass ratio) ethylene glycol monobutyl ether solution is suitable as the reaction medium in oxidation 4-nitrotoluene-2-sulfonic acid to 4,4â²-dinitrostilbene-2,2â²-disulfonic acid. The effect of different aqueous organic solutions on the oxidation reaction was discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 427, 15 November 2016, Pages 303-307
Journal: Fluid Phase Equilibria - Volume 427, 15 November 2016, Pages 303-307
نویسندگان
Wen-Cai Wang, Yang-Yang Zhang-Bian, Guo-Liang Zhang, Qing Xia, Feng-Bao Zhang,