کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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66304 | 48424 | 2011 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Reflux method as a novel route for the synthesis of MoVTeNbOx catalysts for selective oxidation of propane to acrylic acid Reflux method as a novel route for the synthesis of MoVTeNbOx catalysts for selective oxidation of propane to acrylic acid](/preview/png/66304.png)
This work reports the applicability of reflux to the synthesis of Mo–V–Te–Nb–O metal oxide catalysts for the first time. The well-formed and defined orthorhombic M1 phase, i.e. Te2M20O57 (M = Mo, V, Nb), was found to be better developed when a longer time was used to reflux the mixed metal clusters. The catalysts efficient for propane selective oxidation to acrylic acid, reaching ca. 60% of selectivity to acrylic acid at propane conversion of ca. 50% and at a reaction temperature of 693 K. In addition, a parallel between catalytic activity and catalyst reducibility is also concluded.
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► Mo–V–Te–Nb–O metal oxides can be prepared by refluxing the corresponding salts.
► M1 phase is selectively obtained from solids prepared at a refluxing time of 7–14 days.
► Active and selective catalysts for partial oxidation of propane to acrylic acid have been achieved.
Journal: Journal of Molecular Catalysis A: Chemical - Volumes 342–343, 1 June 2011, Pages 50–57