کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6630587 | 1424933 | 2018 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Biogas combustion: Chemiluminescence fingerprint
ترجمه فارسی عنوان
احتراق بیوگاز: اثر انگشت شیمیایی
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کلمات کلیدی
بیوگاز، شیمی معدنی، طیف سنجی، شعله پیش مخلوط، 00-01، 99-00،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
A numerical and experimental study was conducted, with the purpose of inferring the influence of the CO2 concentration (xCO2) for different equivalence ratios (Ï) on CH4/CO2/air (biogas) flames chemiluminescence. A thorough analysis on the signals of OHâ, CHâ, C2â and CO2â was performed. Typical biogas compositions were tested under laminar atmospheric flame conditions, within the unburned equivalence ratio of 0.9 and 1.14 with CO2 concentrations up to 40% in the blend. Experimental measurements of chemiluminescence were done using spectroscopy in the UV-visible region of the spectra. Simulations were performed with the GRI-Mech 3.0 mechanism without accounting for the nitrogen chemistry, extended with a chemiluminescence kinetics of OHâ, CHâ, C2â and CO2â, in a burner-stabilized frame in CANTERA. Experimental measurements and numerical simulations are compared and generally are in good agreement. It was verified that CO2 dilution leads to a regular decrease in the emission intensities of OHâ, CHâ, C2â and CO2â. Relations between chemiluminescence intensity ratios and xCO2 and Ï were found. It was shown that OHâ/CO2â and C2â/CO2â have the potential predict xCO2 in CH4/CO2/air flames. Moreover, it was verified that OHâ/CHâ, OHâ/C2â and CHâ/C2â are well suited to infer Ï for the blends tested. It was verified that xCO2 does not cause relevant changes in the chemiluminescence ratios when inferring Ï.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 231, 1 November 2018, Pages 328-340
Journal: Fuel - Volume 231, 1 November 2018, Pages 328-340
نویسندگان
F.M. Quintino, T.P. Trindade, E.C. Fernandes,