کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6631964 | 1424946 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Catalytic upgrading of pyrolysis vapors from lignite over mono/bimetal-loaded mesoporous HZSM-5
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
HZSM-5 was modified via alkaline treatment and wet impregnation method which loading transition metals (Co, Mo-Co and Ni-Co). The performance of catalysts for the catalytic fast pyrolysis of lignite was tested in a drop tube reactor at 600â¯Â°C. In comparison to non-catalytic experiment, the chemical composition of upgrading tar was obviously simplified, which mainly contains light aromatics such as benzene, toluene, ethylbenzene, xylene and naphthalene (BTEXN). The yield of BTEXN was significantly increased from 12.9 to 26.4â¯mg/g when Ni/Co-H-5 was used. Meanwhile, the Ni/Co-H-5 treated by NaOH solution achieved considerable deoxygenation performance (86.6%) than other ones. The addition of bimetallic Mo-Co or Ni-Co significantly enhanced the BTEXN selectivity of HZSM-5. Ni promoted H2 formation in gaseous product and caused the decrease of naphthalenes yield. Whereas the yields of toluene and o-xylene increased after the pyrolysis vapors pass through Mo/Co-H-5. The zeolite treated by NaOH solution (AT-HZSM-5) favors the generation of aromatics and phenolics, conversely naphthalene derivatives. Moreover, AT-Mo/Co-H-5 and AT-Ni/Co-H-5 inhibited the coke formation. A catalytic pathway was also proposed to describe the diffusion process of pyrolysis vapors on the active site of catalyst.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 218, 15 April 2018, Pages 33-40
Journal: Fuel - Volume 218, 15 April 2018, Pages 33-40
نویسندگان
Xue-Yu Ren, Jing-Pei Cao, Xiao-Yan Zhao, Zhen Yang, Tian-Long Liu, Xing Fan, Yun-Peng Zhao, Xian-Yong Wei,