کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6634981 | 461114 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The application of calcined marlstones as a catalyst in biodiesel production from high free fatty acid coconut oil
ترجمه فارسی عنوان
استفاده از سنگ مرمرهای کاست شده به عنوان کاتالیزور در تولید بیودیزل از روغن نارگیل اسید چرب آزاد
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
The price of biodiesel compared with petrodiesel is sufficiently high to be a deterrent to consumers. By utilising calcium oxide catalysts, the cost of one of the operational inputs, the catalyst amount, can be decreased. These catalysts are derived via calcination from calcium carbonate containing materials such as marlstones. This research investigated the catalytic potential of two types of marlstones in the transesterification of high free fatty acid (FFA) non-edible coconut oil. The marlstones were calcined at 700, 900 and 1000 °C for 1.5, 2 and 3 h. For the transesterification reaction, 5 and 15 wt% catalyst were used at 2 h reaction time, 60 °C and a 6:1 methanol to oil molar ratio in the presence of vigorous stirring. 15 wt% catalyst for both red and white marlstones produced yields ⩾90%. The highest yield of 97% was produced by 15 wt% white marlstones calcined at 1000 °C and 1.5 h, with an additional 6 calcined marlstones producing yields ⩾90%. All marlstones where yield was ⩾90% were fully characterized for surface morphology, elemental analysis, functional group analysis and basicity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 158, 15 October 2015, Pages 372-378
Journal: Fuel - Volume 158, 15 October 2015, Pages 372-378
نویسندگان
Phaedra Jaggernauth-Ali, Ejae John, Puran Bridgemohan,