کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6636356 | 461134 | 2015 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of bituminous coal properties on carbon dioxide and methane high pressure sorption
ترجمه فارسی عنوان
اثر خواص ذغال سنگ بتمن در میزان جذب دی اکسید کربن و متان
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
ذغال سنگ بتمنس، ظرفیت جذب، ترکیب مکرر، حوضه سیلسیای بالایی،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
High pressure sorption experiments with carbon dioxide and methane were carried out at a temperature of 45 °C and at pressures up to 15 MPa with three samples of methane-bearing, medium-rank coals in a moisture-equilibrated state using a manometric method. The samples were taken from selected positions of drill cores from exploration boreholes in the Bohemian part of the Upper Silesian Basin, and were characterized by a narrow range of degree of coalification and markedly different petrographic compositions, including a different mineral matter content. The total porosity of the coal samples was between 9% and 10%. A positive correlation was found between the equilibrium moisture in the coal samples and the total abundance of oxygen functional groups determined by FTIR. The excess sorption capacities ranged from 0.78 to 0.91 mmol gâ1 for CO2 and from 0.45 to 0.52 mmol gâ1 for CH4, and after recalculation to coal organic matter, the excess sorption capacities increased by up to 14% in the coal with the highest mineral fraction. The highest CO2/CH4 ratio was found in the sample that had the highest inertinite and liptinite content. The experimental isotherm data was fitted by modified Langmuir and Dubinin-Radushkevich sorption isotherms. The parameters obtained by these two methods were in good agreement for carbon dioxide. It was found that the sorption capacity of the organic matter in a coal sample with prevalence of inertinite (63.0 vol.%) was lower only by 14% for CO2 and by 18% for CH4 than the sorption capacity of the organic matter in a coal sample with prevalence of vitrinite (65.3 vol.%). This provided confirmation that the petrographic composition of a coal has an ambiguous effect.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 139, 1 January 2015, Pages 115-124
Journal: Fuel - Volume 139, 1 January 2015, Pages 115-124
نویسندگان
Zuzana Weishauptová, OldÅich PÅibyl, Ivana Sýkorová, VladimÃr MachoviÄ,