کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6640016 461153 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Heterogeneous hydrolysis of cellulose into glucose over phenolic residue-derived solid acid
ترجمه فارسی عنوان
هیدرولیز هیدروژن سلولز به گلوکز بیش از اسید جامد مشتق شده از فنل
کلمات کلیدی
باقی مانده فنل، اسید جامد بر پایه کربن، سلولز، هیدرولیز هتروژن، سولفونیت،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
Carbon-based solid acid (CSA) was successfully prepared using phenolic residue as starting material. The characterization results indicate that such solid acid catalyst mainly consists of four building blocks: the condensed aromatic carbon sheets, the active groups (including SO3H, COOH and phenolic OH), the side chains (including CH3 and OCH3) and the bridge linkages (including O, CH2, CH2CH2, and OCH2) acting as the intermediates between aromatic clusters. Most of these building blocks, except for the SO3H, could be derived from the corresponding part of the phenolic residue. Aliphatic side chains have been demonstrated to greatly improve the sulfonation activity of carbon precursor and promote the catalytic performance in cellulose hydrolysis, and the carbon-based catalyst sulfonated for just 1 h could exhibit almost similar catalytic activity compared with the catalyst sulfonated for a longer time. However, their hydrophobicity and steric hindrance reduced the utilization efficiency of the sulfonic acid groups to a certain extent.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 113, November 2013, Pages 644-649
نویسندگان
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