کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
66493 | 48434 | 2011 | 6 صفحه PDF | دانلود رایگان |
The chemical reactivity and reaction mechanism of fluorobenzene formation by dehydrogenation of fluorocyclohexenes was investigated. 1-Fluorocyclohexene reacted with oxidants such as nitrobenzene and oxygen to give fluorobenzene in good yields under moderate conditions in the presence of a Pd catalyst. A detailed comparison of oxidative dehydrogenation with non-oxidative dehydrogenation proved that the oxidants effectively suppressed isomerization and disproportionation, and offered a selective synthesis of fluorobenzene.
The chemical reactivity and reaction mechanism of fluorobenzene formation by dehydrogenation of fluorocyclohexenes are described. The oxidants effectively suppressed isomerization and disproportionation, and offered a selective synthesis of fluorobenzene.Figure optionsDownload high-quality image (73 K)Download as PowerPoint slideResearch highlights
► Pd as dehydrogenation catalyst.
► Catalysts for dehydrogenation of fluorocyclohexenes.
► Fluorobenzene formation by dehydrogenation of fluorocyclohexenes.
► Oxidants effectively suppressed isomerization and disproportionation.
Journal: Journal of Molecular Catalysis A: Chemical - Volume 337, Issues 1–2, 1 March 2011, Pages 89–94