کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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66558 | 48438 | 2011 | 6 صفحه PDF | دانلود رایگان |
In the course of our attempts to replace the traditional but environmentally disfavored organic solvents in organic processes by water, we studied the double bond isomerization of hydrophobic allylarenes, in aqueous microemulsions. The catalyst for these reactions was the rhodium-trichloride-Aliquat® 336 ion pair encaged within hydrophobic silica sol–gel. During the entrapment of the rhodium compound, it was converted into supported catalytically active Rh(0) nanoparticles characterized by TEM and XPS studies. The transformations of the allylarenes to (E)- and (Z)-1-phenyl-1-propenes follows the first order rate law, and proved to be significantly affected by the electronic nature of the substrates and by the hydrophobicity of the sol–gel support. Upon completion of the isomerization the catalyst could be recovered and recycled at least six times without a decrease in the catalytic activity after the first catalytic run.
Isomerization of hydrophobic allylarenes to 1-aryl-1-propenes takes place in aqueous microemulsions by immobilized RhCl3-Aliquat® 336. During the catalytic process the Rh(III) species are converted into Rh(0) nanoparticles.Figure optionsDownload high-quality image (86 K)Download as PowerPoint slideResearch highlights▶ Replacement of organic solvents by aqueous microemulsions. ▶ Catalysis of water insoluble substrates in aqueous media. ▶ Double bond isomerization in allylarenes.
Journal: Journal of Molecular Catalysis A: Chemical - Volume 335, Issues 1–2, 1 February 2011, Pages 8–13