کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6660343 1426222 2015 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Phase equilibrium data for potentially hazardous binary mixtures involving dichlorosilane, trichlorosilane and silicon-tetrachloride
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Phase equilibrium data for potentially hazardous binary mixtures involving dichlorosilane, trichlorosilane and silicon-tetrachloride
چکیده انگلیسی
Isothermal (vapour + liquid) equilibrium data were obtained for potentially hazardous binary mixtures of (dichlorosilane + trichlorosilane), (dichlorosilane + tetrachlorosilane), and (trichlorosilane + tetrachlorosilane) using an apparatus based on the “static-analytic” method. The apparatus was specially developed and designed to ensure safe measurement of the flammable, toxic, and corrosive components. The (dichlorosilane + trichlorosilane) system was measured at T = (343.04, 353.04 and 363.00) K, and the (dichlorosilane + tetrachlorosilane) system at T = (343.28 and 353.07) K, and the (trichlorosilane + tetrachlorosilane) system at T = (323.17, 333.11 and 343.03) K. The resulting data were correlated with the Peng-Robinson equation of state coupled with the Wong Sandler mixing rule. The model provided accurate description of all isotherms of the binary systems using temperature-independent interaction parameters regressed for all isotherms.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 91, December 2015, Pages 420-426
نویسندگان
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