کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6661607 | 1426552 | 2018 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Identification of four isomers of Dihydroxynaphthalene by using a Briggs-Rauscher oscillating system
ترجمه فارسی عنوان
شناسایی چهار ایزومر دی هیدروکسین فتالین با استفاده از یک سیستم نوسان بریگز راوشر
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
A novel method for identification of four isomers of dihydroxynaphthalene (DHN) was reported by their different perturbation effects on a Briggs-Rauscher (BR) oscillating system. In the system, macrocyclic nickel (II) complex NiL(ClO4)2 is used as the catalyst, where the ligand L in the complex is 5,7,7,12,14,14âhexemethylâ1,4,8,11âtetraazacyclotetradecaâ4,11âdiene. By putting equal amount of the same concentrations of four isomers (1,4âdihydroxynaphthalene (1,4-DHN), 1,5âdihydroxynaphthalene (1,5-DHN), 2,3âdihydroxynaphthalene (2,3-DHN) and 2,7âdihydroxynaphthalene (2,7-DHN)) into BR system, the system could or couldn't be perturbed, being reflected in quite different oscillating behaviors after addition of isomers. These four isomers were identified in their concentration range of 5.0â¯Ãâ¯10â6 to 2.5â¯Ãâ¯10â4â¯mol/L. An explanation of such perturbation mechanism is that, 1,4-DHN couldn't be oxidized by BR matrix, but 1,5-DHN, 2,3-DHN and 2,7-DHN could be oxidized by HOO to yield 5âHydroxâ1,4ânaphthoquinone, phthalic acid and 6,7âdihydroxyperyleneâ1,12âquinone (DHPQ), respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 823, 15 August 2018, Pages 378-387
Journal: Journal of Electroanalytical Chemistry - Volume 823, 15 August 2018, Pages 378-387
نویسندگان
Wangning Zhang, Waqar Uddin, Gang Hu, Lin Hu, Zhaohui Fang,