کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6661985 | 1426561 | 2018 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical assay for As (III) by combination of highly thiol-rich trithiocyanuric acid and conductive reduced graphene oxide nanocomposites
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We propose an electrochemical assay for As(III) based on trithiocyanuric acid deposited reduced graphene oxide (TTCA/rGO) using square wave anodic stripping voltammetry (SWASV). In this work, TTCA/rGO is prepared by a simple one-pot method using NaBH4 as the reducing agent. Many TTCA molecules are successfully deposited on the surface of rGO through Ï-Ï conjugation, which endows the TTCA/rGO with excellent adsorption ability of As(III) via AsâS bond. Combining the outstanding conductivity of rGO, the response of electrochemical current for As(III) determination is greatly amplified in the electrochemical detection process. Under optimum conditions, the TTCA/rGO modified gold electrode shows high sensitivity and good selectivity for the detection of As(III) with a low detection limit down to 0.054â¯ppb, which is promising to be applied for the rapid and sensitive determination of As(III) in complicated samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 814, 1 April 2018, Pages 97-103
Journal: Journal of Electroanalytical Chemistry - Volume 814, 1 April 2018, Pages 97-103
نویسندگان
Yan-Hong Yuan, Xiao-Hui Zhu, Shao-Hua Wen, Ru-Ping Liang, Li Zhang, Jian-Ding Qiu,