کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6662169 1426567 2018 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A series of new Phthalocyanine derivatives with large conjugated system as catalysts for the Li/SOCl2 battery
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
A series of new Phthalocyanine derivatives with large conjugated system as catalysts for the Li/SOCl2 battery
چکیده انگلیسی
In order to overcome the disadvantages of Li/SOCl2 battery, such as low voltage and small capacity, a series of phthalocyanine derivatives (MPcOc) as catalysts were added into the electrolyte. In this work, new phthalocyanines were synthesized by the microwave method, and this technique greatly shortened the reaction time. The catalysts were characterized by techniques including the FT-IR, UV-vis, ICP, SEM and XRD. The electrocatalytic performances of the MPcOc to Li/SOCl2 battery were evaluated by electrochemical testing. The synthesized catalysts showed excellent performance with the capacities increasing by 19.34-55.64%. Based on cyclic voltammetry measurements, the function of electrode surface and reaction mechanism were proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 808, 1 January 2018, Pages 8-13
نویسندگان
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