کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6662193 | 1426566 | 2018 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical reduction of terbuthylazine under acidic conditions and structural determination of post-electrolysis product with the aid of GC/MS, IR, and 1H NMR spectroscopy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Terbuthylazine (N-t-butyl-6-chloro-Nâ²-ethyl-1,3,5-triazine-2,4-diamine) is an important chloro-s-triazine herbicide that is used to prevent the growth of weeds during the production of a variety of crops in several European nations. The compound is also used as an algaecide to inhibit the growth of algae in water-cooling ponds and towers in the United States. These compounds can undergo electrochemical reduction under acidic conditions. Reduction pathways for several chloro-s-triazine herbicides have been proposed based on a variety of electrochemical, chromatographic, and spectroscopic techniques. There was general agreement in the literature that protonated forms of these compounds undergo a 4-electron reduction. The proposed reactions were elimination of the chloro group, elimination of an alkyl or alkylamino group, and reduction of the s-triazine ring. The present paper describes an electrochemical study of terbuthylazine with subsequent analyses of the post-electrolysis product by means of GC/MS, IR, and 1H NMR spectroscopy. This work provides evidence for a 4-electron reduction involving elimination of the chloro group and reduction of the s-triazine ring.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 809, 15 January 2018, Pages 125-129
Journal: Journal of Electroanalytical Chemistry - Volume 809, 15 January 2018, Pages 125-129
نویسندگان
Jay H. Brown,