کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6662232 | 1426567 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Coupling of the electrochemical oxidation (EO-BDD)/photocatalysis (TiO2-Fe-N) processes for degradation of acid blue BR dye
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
We report on the successful preparation of Fe-N codoped Titania powders, using TiO2 Degussa P25, salt of Fe (II), and Urea. Modified Titania-based materials were characterized by SEM, EDS, BET, Raman, XRD diffraction and diffuse reflectance UV-vis spectroscopy measurements. The doping of TiO2 induced a shift in the absorption threshold toward the spectral range, obtaining catalysts with a greater photoactivity than the one of pure Degussa P25. The degradation of 200 mL of a solution with 50 mg Lâ 1 acid blue BR dye in sulfate medium at pH 3.0 has been comparatively studied by electrochemical oxidation using a boron doped diamond anode (EO-BDD), Photocatalysis TiO2-Fe-N, and coupled material of EO-BDD/Photocatalysis TiO2-Fe-N. The solution was slowly degraded by EO-BDD (25%) and single Photocatalysis TiO2-Fe-N because of the low rate of dye degradation and its colored by-products with hydroxyl radicals generated at the BDD anode and catalyst surface from water oxidation (29%), whereas the solution was more rapidly degraded using coupled material of EO-BDD/Photocatalysis TiO2-Fe-N (82%), owing to the additional generation of hydroxyl radicals from the photocatalysis of TiO2-Fe-N and BDD anode.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 808, 1 January 2018, Pages 180-188
Journal: Journal of Electroanalytical Chemistry - Volume 808, 1 January 2018, Pages 180-188
نویسندگان
Ulises Morales, Carlos J. Escudero, MarÃa J. Rivero, Inmaculada Ortiz, Juan ManrÃquez Rocha, Juan M. Peralta-Hernández,