Direct extraction of kinetic parameters from experimental cyclic voltammetry

► New method for extraction of kinetic data from experimental voltammetry. ► Method directly yields rate constants as functions of potential. ► No assumptions are made regarding a particular model of electrode kinetics. ► General to all redox systems at electrodes of 'one-dimensional' geometry. ► Shown to work extremely well for the reduction of 2-methyl-2-nitropropane.