کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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66646 | 48443 | 2010 | 6 صفحه PDF | دانلود رایگان |

Hydrolysis of 4-nitrophenyl benzoate (PNPB) in the presence of ionene nanoreactors was studied comparing the ionenes, poly[(dimethyl)-2-hydroxy propanodiyl chloride] (2-OH-33R1), poly[(methylbutyliminium)-2-hydroxy propanodiyl chloride] (2-OH-33R4) and poly[(methyloctyliminium)-2-hydroxy propanodiyl chloride] (2-OH-33R8). Methyl orange incorporation and study of viscosity showed that increase of the side chain length of the ionene enhances the ability to form globular hydrophobic microdomains. Catalytic hydrolysis of PNPB follows the order 2-OH-33R8 ≫ 2-OH-33R4 > 2-OH-33R1, and 2-OH-33R8 has the lowest pKa that may reflect its higher hydrophobicity, which apparently influences the ionene nanoreactor reactivity. A lower pKa indicates easier deprotonation of the alkoxide group, which participates more effectively in the reaction and the 2-OH-33R8 functionalized ionene acts as a specially effective catalytic homogeneous nanoreactor.
Alkaline hydrolysis of 4-nitrophenyl benzoate is efficiently mediated by functionalized ionenes which act as specially effective catalytic homogeneous nanoreactors, concentrating reagents in their hydrophobic microdomains.Figure optionsDownload high-quality image (125 K)Download as PowerPoint slideResearch highlights▶ Functional ionenes act as effective catalytic nanoreactors. ▶ Alkaline hydrolysis of esters efficiently mediated by polysoaps. ▶ Globular nanoreactors form hydrophobic microdomains.
Journal: Journal of Molecular Catalysis A: Chemical - Volume 332, Issues 1–2, 1 November 2010, Pages 7–12